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Molar mass of aluminium chloride (AlCl3)

The molar mass of aluminium chloride, AlCl3, is 133.33 g/mol. One mole of it, which is 6.022 × 1023 formula units, has a mass of 133.33 grams.

133.33 g/mol

26.982 + 3 × 35.45 = 133.332 · 4 atoms in the formula

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About aluminium chloride

Anhydrous aluminium chloride is a white solid that fumes in moist air. It is an important catalyst in organic chemistry, in the Friedel-Crafts reactions.

The working

The formula AlCl3 has 1 aluminium atom and 3 chlorine atoms, 4 atoms in all. Multiply each count by the atomic weight of the element and add:

ElementAtomsAtomic weightTotalShare by mass
Aluminium (Al)126.98226.98220.24%
Chlorine (Cl)335.45106.35079.76%

26.982 + 3 × 35.45 = 133.332 g/mol

With the rounded atomic masses used in many school books (Al = 27, Cl = 35.5) the answer is 133.5 g/mol. The difference from 133.33 is too small to matter in most school sums.

Percentage composition

By mass, AlCl3 is 20.24% aluminium and 79.76% chlorine. The largest share comes from chlorine. In a 100 g sample there are 20.2 g of aluminium and 79.8 g of chlorine.

Worked examples

Grams to moles. How many moles are in 40 g of AlCl3? Divide the mass by the molar mass: 40 ÷ 133.33 = 0.3 mol.

Moles to grams. What is the mass of 3 mol of AlCl3? Multiply: 3 × 133.33 = 400 g.

Counting particles. 40 g contains 0.3 mol × 6.022 × 1023 = 1.807 × 1023 formula units.

Making a solution. A 0.1 mol/L solution contains 0.1 × 133.33 = 13.33 g of AlCl3 in each litre. For 250 mL, weigh 3.333 g and make it up to the mark with water.

Quick conversion tables

AmountMass
0.1 mol13.33 g
0.5 mol66.67 g
1 mol133.3 g
2 mol266.7 g
5 mol666.7 g
MassMoles
1 g0.0075 mol
10 g0.075 mol
100 g0.75 mol
1 kg7.5 mol

For other amounts use the grams and moles converter.

Questions people ask

What is the molar mass of AlCl3?

The molar mass of aluminium chloride (AlCl3) is 133.33 g/mol, or 133.332 g/mol before rounding, using IUPAC abridged atomic weights.

How many moles are in 100 g of AlCl3?

100 ÷ 133.33 = 0.75 mol.

What is the mass of one formula unit of AlCl3?

Divide the molar mass by the Avogadro constant: 133.33 ÷ 6.022 × 1023 = 2.214 × 10-22 g.

What is the percentage of chlorine in AlCl3?

Chlorine makes up 79.76% of the mass of AlCl3: 3 × 35.45 ÷ 133.332 × 100.

Which values? This site uses the abridged standard atomic weights published by IUPAC (CIAAW), read on 12 November 2026. Your textbook or question paper may round them differently, for example H = 1 and O = 16, so its answer can differ slightly. In an exam, use the values the paper gives.

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