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Molar mass of oxygen (O2)

The molar mass of oxygen, O2, is 32.00 g/mol. One mole of it, which is 6.022 × 1023 molecules, has a mass of 32.00 grams.

32.00 g/mol

2 × 15.999 = 31.998 · 2 atoms in the formula · also called dioxygen

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About oxygen

Oxygen gas is made of molecules of two atoms. That is why its molar mass is twice the atomic weight of oxygen. Forgetting the 2 is the most common slip in mole sums about burning.

Other names: dioxygen.

The working

The formula O2 has 2 oxygen atoms. Multiply each count by the atomic weight of the element and add:

ElementAtomsAtomic weightTotalShare by mass
Oxygen (O)215.99931.998100.00%

2 × 15.999 = 31.998 g/mol

With the rounded atomic masses used in many school books (O = 16) the answer is 32 g/mol. The difference from 32.00 is too small to matter in most school sums.

Percentage composition

O2 contains only oxygen, so oxygen makes up 100% of its mass. Each molecule has 2 atoms, which is why the molar mass is 2 times the atomic weight 15.999.

Worked examples

Grams to moles. How many moles are in 5 g of O2? Divide the mass by the molar mass: 5 ÷ 32.00 = 0.1563 mol.

Moles to grams. What is the mass of 0.25 mol of O2? Multiply: 0.25 × 32.00 = 8 g.

Counting particles. 5 g contains 0.1563 mol × 6.022 × 1023 = 9.410 × 1022 molecules, and 1.882 × 1023 atoms in all.

As a gas. At 0 °C and 1 atmosphere one mole of an ideal gas occupies 22.4 litres, so the density of O2 is about 32.00 ÷ 22.4 = 1.43 g per litre. Air averages about 29 g/mol, so this gas is heavier than air.

Quick conversion tables

AmountMass
0.1 mol3.2 g
0.5 mol16 g
1 mol32 g
2 mol64 g
5 mol160 g
MassMoles
1 g0.03125 mol
10 g0.3125 mol
100 g3.125 mol
1 kg31.25 mol

For other amounts use the grams and moles converter.

Questions people ask

What is the molar mass of O2?

The molar mass of oxygen (O2) is 32.00 g/mol, or 31.998 g/mol before rounding, using IUPAC abridged atomic weights.

How many moles are in 100 g of O2?

100 ÷ 32.00 = 3.125 mol.

What is the mass of one molecule of O2?

Divide the molar mass by the Avogadro constant: 32.00 ÷ 6.022 × 1023 = 5.313 × 10-23 g.

Which values? This site uses the abridged standard atomic weights published by IUPAC (CIAAW), read on 12 November 2026. Your textbook or question paper may round them differently, for example H = 1 and O = 16, so its answer can differ slightly. In an exam, use the values the paper gives.

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