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Molar mass of sodium sulphate (Na2SO4)

The molar mass of sodium sulphate, Na2SO4, is 142.04 g/mol. One mole of it, which is 6.022 × 1023 formula units, has a mass of 142.04 grams.

142.04 g/mol

2 × 22.990 + 32.06 + 4 × 15.999 = 142.036 · 7 atoms in the formula · also called sodium sulfate

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About sodium sulphate

Sodium sulphate is a white salt used in making detergents, glass and paper. The decahydrate is called Glauber's salt. In the anhydrous form it is used to dry organic solutions.

Other names: sodium sulfate.

The working

The formula Na2SO4 has 2 sodium atoms, 1 sulphur atom and 4 oxygen atoms, 7 atoms in all. Multiply each count by the atomic weight of the element and add:

ElementAtomsAtomic weightTotalShare by mass
Sodium (Na)222.99045.98032.37%
Sulphur (S)132.0632.06022.57%
Oxygen (O)415.99963.99645.06%

2 × 22.990 + 32.06 + 4 × 15.999 = 142.036 g/mol

With the rounded atomic masses used in many school books (Na = 23, S = 32, O = 16) the answer is 142 g/mol. The difference from 142.04 is too small to matter in most school sums.

Percentage composition

By mass, Na2SO4 is 32.37% sodium, 22.57% sulphur and 45.06% oxygen. The largest share comes from oxygen. In a 100 g sample there are 32.4 g of sodium, 22.6 g of sulphur and 45.1 g of oxygen.

Worked examples

Grams to moles. How many moles are in 50 g of Na2SO4? Divide the mass by the molar mass: 50 ÷ 142.04 = 0.352 mol.

Moles to grams. What is the mass of 0.4 mol of Na2SO4? Multiply: 0.4 × 142.04 = 56.81 g.

Counting particles. 50 g contains 0.352 mol × 6.022 × 1023 = 2.120 × 1023 formula units.

Making a solution. A 0.1 mol/L solution contains 0.1 × 142.04 = 14.2 g of Na2SO4 in each litre. For 250 mL, weigh 3.551 g and make it up to the mark with water.

Quick conversion tables

AmountMass
0.1 mol14.2 g
0.5 mol71.02 g
1 mol142 g
2 mol284.1 g
5 mol710.2 g
MassMoles
1 g0.00704 mol
10 g0.0704 mol
100 g0.704 mol
1 kg7.04 mol

For other amounts use the grams and moles converter.

Questions people ask

What is the molar mass of Na2SO4?

The molar mass of sodium sulphate (Na2SO4) is 142.04 g/mol, or 142.036 g/mol before rounding, using IUPAC abridged atomic weights.

How many moles are in 100 g of Na2SO4?

100 ÷ 142.04 = 0.704 mol.

What is the mass of one formula unit of Na2SO4?

Divide the molar mass by the Avogadro constant: 142.04 ÷ 6.022 × 1023 = 2.359 × 10-22 g.

What is the percentage of oxygen in Na2SO4?

Oxygen makes up 45.06% of the mass of Na2SO4: 4 × 15.999 ÷ 142.036 × 100.

Which values? This site uses the abridged standard atomic weights published by IUPAC (CIAAW), read on 12 November 2026. Your textbook or question paper may round them differently, for example H = 1 and O = 16, so its answer can differ slightly. In an exam, use the values the paper gives.

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