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Molar mass of benzoic acid (C6H5COOH)

The molar mass of benzoic acid, C6H5COOH, is 122.12 g/mol. One mole of it, which is 6.022 × 1023 molecules, has a mass of 122.12 grams.

122.12 g/mol

7 × 12.011 + 6 × 1.0080 + 2 × 15.999 = 122.123 · 15 atoms in the formula

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About benzoic acid

Benzoic acid is a white solid whose sodium salt is a common food preservative. It is often used in school to practise recrystallisation.

The working

The formula C6H5COOH has 7 carbon atoms, 6 hydrogen atoms and 2 oxygen atoms, 15 atoms in all. Multiply each count by the atomic weight of the element and add:

ElementAtomsAtomic weightTotalShare by mass
Carbon (C)712.01184.07768.85%
Hydrogen (H)61.00806.0484.95%
Oxygen (O)215.99931.99826.20%

7 × 12.011 + 6 × 1.0080 + 2 × 15.999 = 122.123 g/mol

With the rounded atomic masses used in many school books (C = 12, H = 1, O = 16) the answer is 122 g/mol. The difference from 122.12 is too small to matter in most school sums.

Percentage composition

By mass, C6H5COOH is 68.85% carbon, 4.95% hydrogen and 26.20% oxygen. The largest share comes from carbon. In a 100 g sample there are 68.8 g of carbon, 5.0 g of hydrogen and 26.2 g of oxygen.

Worked examples

Grams to moles. How many moles are in 25 g of C6H5COOH? Divide the mass by the molar mass: 25 ÷ 122.12 = 0.2047 mol.

Moles to grams. What is the mass of 0.1 mol of C6H5COOH? Multiply: 0.1 × 122.12 = 12.21 g.

Counting particles. 25 g contains 0.2047 mol × 6.022 × 1023 = 1.233 × 1023 molecules, and 1.849 × 1024 atoms in all.

Quick conversion tables

AmountMass
0.1 mol12.21 g
0.5 mol61.06 g
1 mol122.1 g
2 mol244.2 g
5 mol610.6 g
MassMoles
1 g0.008188 mol
10 g0.08188 mol
100 g0.8188 mol
1 kg8.188 mol

For other amounts use the grams and moles converter.

Questions people ask

What is the molar mass of C6H5COOH?

The molar mass of benzoic acid (C6H5COOH) is 122.12 g/mol, or 122.123 g/mol before rounding, using IUPAC abridged atomic weights.

How many moles are in 100 g of C6H5COOH?

100 ÷ 122.12 = 0.8188 mol.

What is the mass of one molecule of C6H5COOH?

Divide the molar mass by the Avogadro constant: 122.12 ÷ 6.022 × 1023 = 2.028 × 10-22 g.

What is the percentage of carbon in C6H5COOH?

Carbon makes up 68.85% of the mass of C6H5COOH: 7 × 12.011 ÷ 122.123 × 100.

Which values? This site uses the abridged standard atomic weights published by IUPAC (CIAAW), read on 12 November 2026. Your textbook or question paper may round them differently, for example H = 1 and O = 16, so its answer can differ slightly. In an exam, use the values the paper gives.

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